I already had "Ok Google, turn on the computer" triggering my TV and Hi-Fi through Home Assistant, but the PC itself was always the missing piece — WOL never played nice with my setup, and I wanted something that worked reliably regardless of BIOS quirks.
Ended up designing a small PCIe card (ESP32-H2 based) that physically simulates pressing the power/reset buttons on the motherboard, powered straight off the PCIe slot's standby rail (3.3Vaux). It shows up in HA as a switch via Zigbee, alongside the rest of my relay-based lighting/shutter setup.
Fully open — schematic, gerbers, and firmware linked below if anyone wants to build their own:
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